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The total cost of all items included on a Shopping Cart is defaulted to a single cost center. The user can, however, allocate portions of the Shopping Cart to other cost centers, or change the default cost center for the entire purchase.
Cost Center Approvers / Approval Groups, or a general ledger account owner, approve Shopping Carts based on line items associated with a designated cost center. The line items are flagged for each approver / approval group.
To assign cost center approvers to organizations, see Cost Centers in the Administer Organizations Help module.